Spectral studies following electron capture in slow ion-atom collisions are reported for the collision systems Kr(q+) + He (q = 7, 8, 9) at 10 keV/q. The work introduces part of the spectroscopy program which is beginning at the University of Uppsala ECR ion source facility. In particular a search was made for the 3d(10)4p2P-3d(9)4S(2)2D transitions in Cu-like Kr. This multiplet was found to give transitions with wavelengths 198.56, 194.65 and 190.97 angstrom for the 3/2-5/2, 3/2-3/2 and 1/2-3/2 components respectively.