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Transient heating of Pd nanoparticles studied by x-ray diffraction with time of arrival photon detection
Deutsch Elekt Synchrotron DESY, Ctr Xray & Nano Sci CXNS, Notke Str 85, D-22607 Hamburg, Germany.;Rice Univ, Dept Elect & Comp Engn, Houston, TX 77005 USA..
Deutsch Elekt Synchrotron DESY, Ctr Xray & Nano Sci CXNS, Notke Str 85, D-22607 Hamburg, Germany..
Deutsch Elekt Synchrotron DESY, Notke Str 85, D-22607 Zeuthen, Germany..ORCID iD: 0000-0001-9288-4859
Mid Sweden University, Faculty of Science, Technology and Media, Department of Computer and Electrical Engineering (2023-). Deutsch Elekt Synchrotron DESY.ORCID iD: 0000-0003-2304-667X
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2024 (English)In: Structural Dynamics, E-ISSN 2329-7778, Vol. 11, no 4, article id 044301Article in journal (Refereed) Published
Abstract [en]

Pulsed laser heating of an ensemble of Pd nanoparticles, supported by a MgO substrate, is studied by x-ray diffraction. By time-resolved Bragg peak shift measurements due to thermal lattice expansion, the transient temperature of the Pd nanoparticles is determined, which quickly rises by at least 100 K upon laser excitation and then decays within 90 ns. The diffraction experiments were carried out using a Cu x-ray tube, giving continuous radiation, and the hybrid pixel detector Timepix3 operating with single photon counting in a time-of-arrival mode. This type of detection scheme does not require time-consuming scanning of the pump-probe delay. The experimental time resolution is estimated at 15 +/- 5 ns, which is very close to the detector's limit and matches with the 7 ns laser pulse duration. Compared to bulk metal single crystals, it is discussed that the maximum temperature reached by the Pd nanoparticles is higher and their cooling rate is lower. These effects are explained by the oxide support having a lower heat conductivity.

Place, publisher, year, edition, pages
AIP Publishing , 2024. Vol. 11, no 4, article id 044301
National Category
Atom and Molecular Physics and Optics
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URN: urn:nbn:se:miun:diva-52058DOI: 10.1063/5.0189052ISI: 001262132200001PubMedID: 38974812Scopus ID: 2-s2.0-85198005942OAI: oai:DiVA.org:miun-52058DiVA, id: diva2:1887394
Available from: 2024-08-07 Created: 2024-08-07 Last updated: 2025-09-25Bibliographically approved

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Graafsma, Heinz

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