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Laser-formed nanoporous graphite anodes for enhanced lithium-ion battery performance
Mittuniversitetet, Fakulteten för naturvetenskap, teknik och medier, Institutionen för ingenjörsvetenskap, matematik och ämnesdidaktik (2023-).ORCID-id: 0009-0003-3972-1227
Mittuniversitetet, Fakulteten för naturvetenskap, teknik och medier, Institutionen för ingenjörsvetenskap, matematik och ämnesdidaktik (2023-).ORCID-id: 0000-0003-2965-0288
Mittuniversitetet, Fakulteten för naturvetenskap, teknik och medier, Institutionen för ingenjörsvetenskap, matematik och ämnesdidaktik (2023-).ORCID-id: 0000-0001-9137-3440
Mittuniversitetet, Fakulteten för naturvetenskap, teknik och medier, Institutionen för ingenjörsvetenskap, matematik och ämnesdidaktik (2023-).ORCID-id: 0000-0002-7057-5139
2024 (Engelska)Ingår i: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 125, nr 18, artikel-id 181903Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Lithium-ion batteries are pivotal in modern energy storage, commonly utilizing graphite anodes for their high theoretical capacity and long cycle life. However, graphite anodes face inherent limitations, such as restricted lithium-ion storage capacity and slow diffusion rates. Enhancing the porosity of graphite and increasing d-spacing in expanded graphite anodes have been explored to improve lithium-ion diffusion and intercalation. Recent advancements suggest that nanoscale modifications, such as utilizing nano-graphite and graphene, can further enhance performance. Laser processing has emerged as a promising technique for synthesizing and modifying graphite and graphene-related materials, offering control over surface defects and microstructure. Here, we demonstrate an industrially compatible one-step laser processing method to transform a nano-graphite and graphene mixture into a nanoporous matrix, significantly improving lithium-ion battery performance. The laser-processed anodes demonstrated significantly enhanced specific capacities at all charge rates, with improved relative performance at higher charge rates. Additionally, long-term cycling at 1 C showed that laser-processed cells outperformed their non-processed counterparts, with specific capacities of 323 and 241 mAh/g, respectively.

Ort, förlag, år, upplaga, sidor
AIP Publishing , 2024. Vol. 125, nr 18, artikel-id 181903
Nationell ämneskategori
Materialkemi
Identifikatorer
URN: urn:nbn:se:miun:diva-53103DOI: 10.1063/5.0230156ISI: 001345847600006Scopus ID: 2-s2.0-85209352848OAI: oai:DiVA.org:miun-53103DiVA, id: diva2:1913750
Tillgänglig från: 2024-11-15 Skapad: 2024-11-15 Senast uppdaterad: 2025-09-25Bibliografiskt granskad
Ingår i avhandling
1. Optimizing laser processing for the production of advanced materials
Öppna denna publikation i ny flik eller fönster >>Optimizing laser processing for the production of advanced materials
2024 (Engelska)Licentiatavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Lasers, with their unparalleled precision and control, have become vital tools across numerous industries, offering transformative potential for the development of advanced materials. In this research, laser-assisted techniques were employed to develop and optimize functional materials for industrial and energy applications. By leveraging the unique properties of laser light, significant advancements were achieved in three key areas. First, selective laser sintering was employed to create electrically conductive polymer-graphene composites, demonstrating promising electrical conductivity, crucial for applications requiring electromagnetic compatibility. Second, rare-earth-doped nanocrystals were synthesized using ultrashort laser pulses, achieving precise control over nanoparticle size and morphology while maintaining consistent stoichiometry with the bulk material. This synthesis offers potential for applications in photonics due to the stability and tailored properties of the nanocrystal. Third, laser-assisted processing was applied to modify nanographite and nanographite-silicon composite anode materials for lithium-ion batteries. The laser-induced nanoporous structure in graphite-based anodes led to significant improvements in fast charging capabilities and specific capacity. Additionally, the optimization of silicon distribution within the nanographite matrix enhanced battery performance and cycling stability. These findings illustrate the versatility and efficacy of laser-assisted processing in tailoring material properties to meet the growing demands of advanced applications, offering a pathway to the development of next-generation materials with enhanced functionalities.

Ort, förlag, år, upplaga, sidor
Sundsvall: Mid Sweden University, 2024. s. 59
Serie
Mid Sweden University licentiate thesis, ISSN 1652-8948 ; 207
Nyckelord
laser processing, nanoparticles, lithium-ion batteries, selective laser sintering, laser ablation in liquid, graphite anode
Nationell ämneskategori
Materialteknik
Identifikatorer
urn:nbn:se:miun:diva-53391 (URN)978-91-89786-89-9 (ISBN)
Presentation
2025-01-15, O102, Holmgatan 10, Sundsvall, 10:00 (Engelska)
Opponent
Handledare
Tillgänglig från: 2024-12-19 Skapad: 2024-12-18 Senast uppdaterad: 2025-09-25Bibliografiskt granskad

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Bond, LukeAndersson, HenrikHummelgård, MagnusEngholm, Magnus

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