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Combined Heterogeneous Metal/Chiral Amine: Multiple Relay Catalysis for Versatile Eco-Friendly Synthesis
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden.
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden.
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.ORCID iD: 0000-0002-5108-6487
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2014 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 53, no 13, p. 3447-3451Article in journal (Refereed) Published
Abstract [en]

Herein is described a versatile and broad synergistic strategy for expansion of chemical space and the synthesis of valuable molecules (e.g. carbocycles and heterocycles), with up to three quaternary stereocenters, in a highly enantioselective fashion from simple alcohols (31examples, 95:5 to >99.5:0.5 e.r.) using integrated heterogeneous metal/chiral amine multiple relay catalysis and air/O-2 as the terminal oxidant. A novel highly 1,4-selective heterogeneous metal/amine co-catalyzed hydrogenation of enals was also added to the relay catalysis sequences.

Place, publisher, year, edition, pages
2014. Vol. 53, no 13, p. 3447-3451
Keywords [en]
alcohols, heterogeneous catalysis, homogeneous catalysis, hydrogenation, oxidation
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:miun:diva-21995DOI: 10.1002/anie.201310216ISI: 000333001500028Scopus ID: 2-s2.0-84896451294OAI: oai:DiVA.org:miun-21995DiVA, id: diva2:721586
Available from: 2014-06-04 Created: 2014-05-28 Last updated: 2017-12-05Bibliographically approved

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Afewerki, SamsonCordova, Armando

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