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One-pot highly enantioselective catalytic Mannich-type reactions between aldehydes and stable a-amido sulfones: Asymmetric synthesis of b-amino aldehydes and b-amino acids
(Armando Córdova)
(Armando Córdova)
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2010 (English)In: Tetrahedron Letters, ISSN 0040-4039, E-ISSN 1359-8562, Vol. 51, no 2, p. 234-237Article in journal (Refereed) Published
Abstract [en]

A highly enantioselective catalytic route to carbamate- and benzoate-protected β-amino aldehydes and β-amino acids is presented. The amino acid-catalyzed one-pot asymmetric reaction between unmodified aldehydes and α-amido sulfones gives the corresponding β-amino compounds with up to 95:5 dr and 97–>99% ee.

Place, publisher, year, edition, pages
2010. Vol. 51, no 2, p. 234-237
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Organic Chemistry
Identifiers
URN: urn:nbn:se:miun:diva-15147DOI: 10.1016/j.tetlet.2009.10.130OAI: oai:DiVA.org:miun-15147DiVA, id: diva2:463776
Available from: 2011-12-11 Created: 2011-12-11 Last updated: 2017-12-08Bibliographically approved

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