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Highly Enantioselective Co-Catalytic Direct Aldol reactions by Combination of Hydrogen-Bond Donating and Acyclic Amino Acid Catalysts
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences, Engineering and Mathematics. (Armando Córdova)
Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden .
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences, Engineering and Mathematics.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences, Engineering and Mathematics. (Armando Córdova)
2011 (English)In: Advanced Synthesis and Catalysis, ISSN 1615-4150, E-ISSN 1615-4169, Vol. 353, no 17, p. 3114-3122Article in journal (Refereed) Published
Abstract [en]

Highly enantioselective co-catalytic direct aldol reactions by a combination of simple hydrophobic acyclic amino acid and hydrogen-bond donating catalysts are presented. The corresponding aldol products are formed in high yields with high regio-, diastereo- (anti or syn) and enantioselectivity (up to 99.5:0.5 er). The catalyst loadings can be decreased to as little as 2 mol%.

Place, publisher, year, edition, pages
2011. Vol. 353, no 17, p. 3114-3122
Keyword [en]
aldol reaction, amino acids, asymmetric catalysis, co-catalysis, hydrogen-bond donating
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:miun:diva-14751DOI: 10.1002/adsc.201100408ISI: 000298171500007Scopus ID: 2-s2.0-82055208588OAI: oai:DiVA.org:miun-14751DiVA, id: diva2:457152
Available from: 2011-11-17 Created: 2011-11-17 Last updated: 2017-12-08Bibliographically approved

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Ma, GuangningIbrahem, IsmailCórdova, Armando

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