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Organocatalytic enantioselective aziridination of α-substituted α,β-unsaturated aldehydes: Asymmetric synthesis of terminal aziridines
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2010 (English)In: Advanced Synthesis and Catalysis, ISSN 1615-4150, E-ISSN 1615-4169, Vol. 352, no 18, p. 3201-3207Article in journal (Refereed) Published
Abstract [en]

The first example of a highly enantioselective organocatalytic aziridination of α-substituted α,β-unsaturated aldehydes is presented. The reaction is catalyzed by simple chiral amines and gives access to highly functional terminal azirdines containing an α-tertiary amine stereocenter in high yields and enantiomeric ratios (95.5:4.5-98:2)

Place, publisher, year, edition, pages
2010. Vol. 352, no 18, p. 3201-3207
Keywords [en]
α-substituted α, β-unsaturated aldehydes; asymmetric catalysis; domino reactions; organocatalysis; terminal aziridines
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:miun:diva-12919DOI: 10.1002/adsc.201000650ISI: 000285397800019Scopus ID: 2-s2.0-78650313899OAI: oai:DiVA.org:miun-12919DiVA, id: diva2:383026
Available from: 2011-01-03 Created: 2011-01-03 Last updated: 2017-12-11Bibliographically approved

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Còrdova, Armando

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