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Chemoenzymatic preparation of (2S, 3S)- and (2R, 3R)-2,3-butanediols and their esters from mixtures of d,l- and meso-diols
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
2001 (English)In: Tetrahedron: Asymmetry, ISSN 0957-4166, Vol. 12, no 5, 771-778 p.Article in journal (Refereed) Published
Abstract [en]

An efficient method of preparing the pure enantiomers of 2,3-butanediol front commercially available mixtures of the d,l- and meso-isomers was developed. It furnished (2S,3S)-2.3-butanediol with > 99% e.e. and a >9.5/0.5 diastereomeric ratio and (2R,3R)-2,3-butanediol in 95% e.e. and >9.5/<5 diastereomeric ratio.

Place, publisher, year, edition, pages
2001. Vol. 12, no 5, 771-778 p.
Keyword [en]
Lipase catalysed resolution of 2, 3-butanediol
National Category
Chemical Sciences Industrial Biotechnology
Identifiers
URN: urn:nbn:se:miun:diva-4077DOI: 10.1016/S0957-4166(01)00109-4ISI: 000168596200015Scopus ID: 2-s2.0-0035794283Local ID: 4597OAI: oai:DiVA.org:miun-4077DiVA: diva2:29109
Available from: 2008-09-30 Created: 2008-09-30 Last updated: 2016-10-17Bibliographically approved

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