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Diastereoselective addition of chiral azomethine ylides to cinnamoyl moieties, attached to chiral auxiliaries
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
2001 (English)In: Tetrahedron: Asymmetry, ISSN 0957-4166, Vol. 12, no 14, 1975-1976 p.Article in journal (Refereed) Published
Abstract [en]

Doubly diastereoselective 1,3-dipolar cycloadditions of chiral azomethine ylides to cinnamoyl moieties, attached to chiral auxiliaries, were investigated. The resulting trans-3,4-disubstituted pyrrolidines were obtained in diastereomeric ratios of up to 78:22. The influence on this ratio by the constitution of the chiral ylide was found to be rather small.

Place, publisher, year, edition, pages
2001. Vol. 12, no 14, 1975-1976 p.
Keyword [en]
Dipolar cycloadditions
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:miun:diva-4076DOI: 10.1016/S0957-4166(01)00366-4ISI: 000171514000005Scopus ID: 2-s2.0-0035859708Local ID: 4596OAI: oai:DiVA.org:miun-4076DiVA: diva2:29108
Available from: 2008-09-30 Created: 2008-09-30 Last updated: 2016-10-17Bibliographically approved

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Karlsson, StaffanHögberg, Hans-Erik
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