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Quantum beats in singlet-triplet transitions of radical pairs induced by a radio-frequency field
Institute of Chemical Kinetics and Combustion, Novosibirsk 630090, USSR.
1990 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 165, no 2-3, p. 142-145Article in journal (Refereed) Published
Abstract [en]

This Letter reports on the experimental observation of quantum beats stimulated by a resonance radio-frequency field in the recombination luminescence of radical-ion pairs. The beat frequency for solutions of p-terphenyl in squalane increases linearly with rf-field amplitude in the range 1 to 10 G in a rotating frame. The beat frequency corresponds to the theoretically calculated one, with amplitude twice as low as the theoretical one. This is attributed to contributions from the recombination of spin-uncorrelated radical-ion pairs

Place, publisher, year, edition, pages
Amsterdam: Elsevier Science , 1990. Vol. 165, no 2-3, p. 142-145
Keywords [en]
Experimental study ; Luminescence ; Singlet triplet transition ; Quantum beat ; Ion radical recombination ; Radiofrequency irradiation ; Ion pair ; Organic free radical ; Organic compounds ; Chemical solution ; Kinetics
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:miun:diva-10074DOI: 10.1016/0009-2614(90)85419-DOAI: oai:DiVA.org:miun-10074DiVA, id: diva2:272983
Available from: 2009-10-19 Created: 2009-10-19 Last updated: 2017-12-12Bibliographically approved

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Koptioug, Andrei

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