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Bond-length-dependent core hole localization observed in simple hydrocarbons
Mid Sweden University.
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1999 (English)In: Physical Review Letters, ISSN 0031-9007, Vol. 83, no 7, 1315-1318 p.Article in journal (Refereed) Published
Abstract [en]

Soft x-ray-emission spectroscopy is applied to measure the amount of dynamic symmetry breaking in core-excited acetylene, ethylene, and ethane. Large variations are observed between the molecules and are rationalized in terms of the different C-C bond lengths: Shorter bond lengths give smaller symmetry breaking. The results also indicate that asymmetric modes are important for all the systems studied, in contradiction to previous assumptions in literature.

Place, publisher, year, edition, pages
1999. Vol. 83, no 7, 1315-1318 p.
Keyword [en]
X-RAY-EMISSION, K-SHELL EXCITATION, PHOTOELECTRON-SPECTRA, SYMMETRY-BREAKING, HIGH-RESOLUTION, VIBRATIONAL STRUCTURE, SPECTROSCOPY, SCATTERING, IONIZATION, ETHENE
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:miun:diva-2078ISI: 000082066600011Local ID: 1086OAI: oai:DiVA.org:miun-2078DiVA: diva2:27110
Available from: 2008-09-30 Created: 2008-09-30 Last updated: 2011-01-10Bibliographically approved

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