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Bile Salts Form Lyotropic Liquid Crystals
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
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2003 (English)In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, ISSN 0927-7757, E-ISSN 1873-4359, Vol. 213, no 1, 79-92 p.Article in journal (Refereed) Published
Abstract [en]

A reinvestigation of the phase diagrams relative to some conjugated and non-conjugated bile salts in water has demonstrated the formation of lyotropic liquid crystalline phases, in contradiction with generally accepted statements. The phase behaviour is complex and the phase diagrams are unusual, compared to most surfactants and lipids. In particular, coexistence of liquid crystalline phases with crystals has been observed. The formation of liquid crystalline phases requires very long equilibration times and the thermal stability of the lyotropic phases is moderate. The observed structure is tentatively assumed to be of the reverse hexagonal type. Structural relations with currently accepted models for the organisation of bile salts into micelles and solid form have been found.

Place, publisher, year, edition, pages
2003. Vol. 213, no 1, 79-92 p.
Keyword [sv]
gallsalt, surfaktanter, flytande kristallina faser
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:miun:diva-1841DOI: 10.1016/S0927-7757(02)00360-6ISI: 000182771400009Scopus ID: 2-s2.0-0346033458Local ID: 605OAI: oai:DiVA.org:miun-1841DiVA: diva2:26873
Available from: 2008-09-30 Created: 2008-09-30 Last updated: 2016-10-05Bibliographically approved

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Edlund, Håkan
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