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Transformation of alpha-pinene using Picea abies suspension culture
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
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2003 (English)In: Journal of Natural Products, ISSN 0163-3864, Vol. 66, no 3, 337-343 p.Article in journal (Refereed) Published
Abstract [en]

alpha-Pinene, both as the pure enantiomers and as the racemate, was transformed mainly to trans-verbenol by treatment with a Picea abies suspension cell culture. These reactions were followed by a slow transformation of the verbenol to verbenone, which was not transformed further. trans-Pinocarveol, myrtenol, cis-verbenol, and alpha-terpineol were byproducts of intermediate abundance. When subjected to the action of the suspension culture, cis-verbenol was not only transformed to verbenone but also isomerized to trans-verbenol. The transformation of alpha-pinene was fast, and the products were detected within one minute. The absolute configuration of the major products corresponded to that of the starting alpha-pinene enantiomer

Place, publisher, year, edition, pages
2003. Vol. 66, no 3, 337-343 p.
Keyword [en]
Suspension Culture
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:miun:diva-1538DOI: 10.1021/np020426mISI: 000181923100004Scopus ID: 2-s2.0-0037349145Local ID: 440OAI: oai:DiVA.org:miun-1538DiVA: diva2:26570
Available from: 2008-09-30 Created: 2008-09-30 Last updated: 2016-10-21Bibliographically approved

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Lindmark-Henriksson, MaricaIsaksson, DanSjödin, KristinaHögberg, Hans-Erik
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