Optimization of lithium adsorption from seawater via aluminum chloride as adsorbent using response surface methodology Show others and affiliations
2024 (English) In: Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, ISSN 1556-7036, E-ISSN 1556-7230, Vol. 46, no 1, p. 2907-2921Article in journal (Refereed) Published
Abstract [en]
Lithium extraction from natural resources is an accelerating field of research owing to its growing demand in the medical, nuclear, battery, and air conditioning industries. Lithium compounds are used in various industries, including ceramics, glass, lubricant gases, rocket propellant, and aluminum production. The extraction of lithium from seawater via adsorption using AlCl3.6 H2O as an adsorbent is investigated in this study. The effect of process parameters such as pH, temperature, contact time, the molar ratio ([Al3+]/[Li+]), and stirring rate on process efficiency is investigated and optimized. The response surface methodology (RSM) is used to investigate the effects of operating parameters and choose the optimal configuration. A standard synthetic solution containing 50 ppm lithium is prepared and experimented with facilitating comprehension of the procedure. The adsorption efficiency of a synthetic solution is 88% at optimized values, while that of seawater is 78.5%. Seawater has a lower efficiency because it contains ions such as Mg2+, Ca2+, K+, and Na+ that compete for active points/sites during adsorption with lithium ions (Li+).
Place, publisher, year, edition, pages Informa UK Limited , 2024. Vol. 46, no 1, p. 2907-2921
Keywords [en]
Adsorption, lithium, optimization, response surface approach, seawater
National Category
Energy Engineering
Identifiers URN: urn:nbn:se:miun:diva-50599 DOI: 10.1080/15567036.2024.2310742 ISI: 001158664200001 Scopus ID: 2-s2.0-85184390828 OAI: oai:DiVA.org:miun-50599 DiVA, id: diva2:1839176
2024-02-202024-02-202024-02-23 Bibliographically approved