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Electrochemically Controlled Hydrogels with Electrotunable Permeability and Uniaxial Actuation
Department of Fibre and Polymer Technology School of Engineering Sciences in Chemistry Biotechnology and Health KTH Royal Institute of Technology Stockholm 100 44 Sweden.ORCID iD: 0000-0003-4388-8970
Department of Fibre and Polymer Technology School of Engineering Sciences in Chemistry Biotechnology and Health KTH Royal Institute of Technology Stockholm 100 44 Sweden.ORCID iD: 0000-0001-6403-2755
Robotic Materials Department Max Planck Institute for Intelligent Systems 70569 Stuttgart Germany.ORCID iD: 0000-0002-0588-6993
Department of Management and Engineering Division of Solid Mechanics Linköping University Linköping 58183 Sweden.ORCID iD: 0000-0002-1503-8293
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2023 (English)In: Advanced Materials, ISSN 0935-9648, E-ISSN 1521-4095, Vol. 35, no 45, article id 2303255Article in journal (Refereed) Published
Abstract [en]

The unique properties of hydrogels enable the design of life-like soft intelligent systems. However, stimuli-responsive hydrogels still suffer from limited actuation control. Direct electronic control of electronically conductive hydrogels can solve this challenge and allow direct integration with modern electronic systems. An electrochemically controlled nanowire composite hydrogel with high in-plane conductivity that stimulates a uniaxial electrochemical osmotic expansion is demonstrated. This materials system allows precisely controlled shape-morphing at only −1 V, where capacitive charging of the hydrogel bulk leads to a large uniaxial expansion of up to 300%, caused by the ingress of ≈700 water molecules per electron–ion pair. The material retains its state when turned off, which is ideal for electrotunable membranes as the inherent coupling between the expansion and mesoporosity enables electronic control of permeability for adaptive separation, fractionation, and distribution. Used as electrochemical osmotic hydrogel actuators, they achieve an electroactive pressure of up to 0.7 MPa (1.4 MPa vs dry) and a work density of ≈150 kJ m−3 (2 MJ m−3 vs dry). This new materials system paves the way to integrate actuation, sensing, and controlled permeation into advanced soft intelligent systems.

Place, publisher, year, edition, pages
Wiley , 2023. Vol. 35, no 45, article id 2303255
National Category
Polymer Chemistry
Identifiers
URN: urn:nbn:se:miun:diva-49879DOI: 10.1002/adma.202303255Scopus ID: 2-s2.0-85167722724OAI: oai:DiVA.org:miun-49879DiVA, id: diva2:1813038
Funder
Knut and Alice Wallenberg Foundation, 2019.0564Olle Engkvists stiftelseAvailable from: 2023-11-18 Created: 2023-11-18 Last updated: 2023-11-20Bibliographically approved

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Lindström, Stefan B

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Benselfelt, TobiasShakya, JyotiRothemund, PhilippLindström, Stefan BPiper, AndrewWinkler, Thomas E.Hajian, AlirezaWågberg, LarsKeplinger, ChristophHamedi, Mahiar Max
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