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A sustainable strategy for production and functionalization of nanocelluloses
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.ORCID iD: 0000-0002-5108-6487
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
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2019 (English)In: Pure and Applied Chemistry, ISSN 0033-4545, E-ISSN 1365-3075, Vol. 91, no 5, p. 865-874Article in journal (Refereed) Published
Abstract [en]

A sustainable strategy for the neat production and surface functionalization of nanocellulose from wood pulp is disclosed. It is based on the combination of organocatalysis and click chemistry ("organoclick" chemistry) and starts with nanocellulose production by organic acid catalyzed hydrolysis and esterification of the pulp under neat conditions followed by homogenization. This nanocellulose fabrication route is scalable, reduces energy consumption and the organic acid can be efficiently recycled. Next, the surface is catalytically engineered by "organoclick" chemistry, which allows for selective and versatile attachment of different organic molecules (e.g. fluorescent probes, catalyst and pharmaceuticals). It also enables binding of metal ions and nanoparticles. This was exemplified by the fabrication of a heterogeneous nanocellulose-palladium nanoparticle catalyst, which is used for Suzuki cross-coupling transformations in water. The disclosed surface functionalization methodology is broad in scope and applicable to different nanocelluloses and cellulose based materials as well.

Place, publisher, year, edition, pages
2019. Vol. 91, no 5, p. 865-874
Keywords [en]
click chemistry, cross-coupling reaction, heterogeneous catalysis, nanocellulose, NICE-2016, organocatalysis, surface engineering
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:miun:diva-35142DOI: 10.1515/pac-2018-0204ISI: 000466859500008Scopus ID: 2-s2.0-85056591870OAI: oai:DiVA.org:miun-35142DiVA, id: diva2:1269419
Available from: 2018-12-10 Created: 2018-12-10 Last updated: 2019-07-08Bibliographically approved

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Cordova, ArmandoAfewerki, SamsonAlimohammadzadeh, RanaSanhueza, ItaloOsong, Sinke H.Engstrand, PerIbrahem, Ismail

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Cordova, ArmandoAfewerki, SamsonAlimohammadzadeh, RanaSanhueza, ItaloOsong, Sinke H.Engstrand, PerIbrahem, Ismail
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