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Copper Nanoparticles on Controlled Pore Glass and TEMPO for the Aerobic Oxidation of Alcohols
Mid Sweden University, Faculty of Science, Technology and Media, Department of Chemical Engineering. (FSCN)
Stockholm University.
Stockholm University.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Chemical Engineering. (FSCN)ORCID iD: 0000-0001-6270-2970
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2018 (English)In: ChemNanoMat, ISSN 2199-692X, Vol. 4, no 1, p. 71-75Article in journal (Refereed) Published
Abstract [en]

Herein, we report on the facile synthesis of a heterogeneous copper nanocatalyst and its combination with 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) for the aerobic oxidation of alcohols to their corresponding carbonyl compounds. This low cost copper nanocatalyst was found to exhibit excellent recyclability, making it a highly attractive catalytic system from an economical and environmental point of view. Extensive characterization of the catalyst by a number of techniques revealed that it was comprised of well-dispersed Cu(I/II) nanoparticles with an average size of around 6nm.

Place, publisher, year, edition, pages
2018. Vol. 4, no 1, p. 71-75
Keyword [en]
Alcohol oxidation, Copper nanoparticles, Green chemistry, Heterogeneous catalysis, TEMPO
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:miun:diva-32328DOI: 10.1002/cnma.201700309ISI: 000419237800011OAI: oai:DiVA.org:miun-32328DiVA: diva2:1163705
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Version of record online: 14 November 2017

Available from: 2017-12-07 Created: 2017-12-07 Last updated: 2018-01-25Bibliographically approved

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Ibrahem, IsmailEivazihollagh, AlirezaEdlund, HåkanNorgren, Magnus

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