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Direct regiospecific and highly enantioselective intermolecular a-allylic alkylation of aldehydes by combination of transition metal and chiral amine catalysts
Mittuniversitetet, Fakulteten för naturvetenskap, teknik och medier, Institutionen för tillämpad naturvetenskap och design. (Armando Córdova)ORCID-id: 0000-0002-5108-6487
2012 (engelsk)Konferansepaper, Poster (with or without abstract) (Fagfellevurdert)
Abstract [en]

The direct intermolecular regiospecific and highly enantioselective a-allylic alkylation of linear aldehydes by combination of achiral bench stable Pd(0) complexes and simple chiral amines as co-catalysts is disclosed. The co-catalytic asymmetric chemoselective and regiospecific a-allylic alkylation reaction is linked in tandem with in situ reduction to give the corresponding 2-alkyl alcohols with high enantiomeric ratios (up to 98:2 er). It is also an expeditious entry to valuable 2-alkyl substituted hemiacetals and 2-alkyl-butane-1,4-diols.

sted, utgiver, år, opplag, sider
2012.
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URN: urn:nbn:se:miun:diva-16700OAI: oai:DiVA.org:miun-16700DiVA, id: diva2:543940
Konferanse
ORGANIKERDAGARNA XXIII, 12-15 JUNE 2012 CONFERENCE CENTER WALLENBERG GÖTEBORG
Tilgjengelig fra: 2012-08-11 Laget: 2012-08-11 Sist oppdatert: 2016-09-29bibliografisk kontrollert

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