In LaserMaterial Processing, an understanding of the fundamental absorption mechanisms plays a vital role in determining the optimum processing parameters and conditions. The absorptance, which characterizes how much a material absorbs, can alter during a processing application, as a result of melting, boiling, structural changes of the surface, oxidation, plasma formation, etc. To gain knowledge of these complex processes, a combination of experimental as well as of theoretical work is required. In this paper, an overview of the most common experimental methods and techniques to measure laser absorption in opaque solids, such as metals, will be presented.