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Assigning x-ray absorption spectra by means of soft-x-ray emission spectroscopy
Mittuniversitetet.
Vise andre og tillknytning
1998 (engelsk)Inngår i: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, Vol. 57, nr 2, s. 864-872Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The possibility to symmetry assign x-ray absorption spectra using x-ray emission spectroscopy is demonstrated. The oxygen K spectra of CO2 are used to illustrate the possibility to assign core excitations through excitation-energy and angular dependence of resonantly excited x-ray emission spectra. The Rydberg-associated structures just below the ionization threshold in the O K x-ray absorption spectrum are assigned to be mainly due to excitations to orbitals of sigma(g) character. The results, which contradict some previous literature assignments, are supported by quantum-chemical calculations.

sted, utgiver, år, opplag, sider
1998. Vol. 57, nr 2, s. 864-872
Emneord [en]
HIGH-RESOLUTION, SYMMETRY-BREAKING, MOLECULAR-OXYGEN, STATIC EXCHANGE, CO2, POLARIZATION, FLUORESCENCE, ANISOTROPY, RESONANCES
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Identifikatorer
URN: urn:nbn:se:miun:diva-2085Lokal ID: 1093OAI: oai:DiVA.org:miun-2085DiVA, id: diva2:27117
Tilgjengelig fra: 2008-09-30 Laget: 2008-09-30 Sist oppdatert: 2011-01-10bibliografisk kontrollert

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