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Bond-length-dependent core hole localization observed in simple hydrocarbons
Mittuniversitetet.
Vise andre og tillknytning
1999 (engelsk)Inngår i: Physical Review Letters, ISSN 0031-9007, Vol. 83, nr 7, s. 1315-1318Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Soft x-ray-emission spectroscopy is applied to measure the amount of dynamic symmetry breaking in core-excited acetylene, ethylene, and ethane. Large variations are observed between the molecules and are rationalized in terms of the different C-C bond lengths: Shorter bond lengths give smaller symmetry breaking. The results also indicate that asymmetric modes are important for all the systems studied, in contradiction to previous assumptions in literature.

sted, utgiver, år, opplag, sider
1999. Vol. 83, nr 7, s. 1315-1318
Emneord [en]
X-RAY-EMISSION, K-SHELL EXCITATION, PHOTOELECTRON-SPECTRA, SYMMETRY-BREAKING, HIGH-RESOLUTION, VIBRATIONAL STRUCTURE, SPECTROSCOPY, SCATTERING, IONIZATION, ETHENE
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Identifikatorer
URN: urn:nbn:se:miun:diva-2078ISI: 000082066600011Lokal ID: 1086OAI: oai:DiVA.org:miun-2078DiVA, id: diva2:27110
Tilgjengelig fra: 2008-09-30 Laget: 2008-09-30 Sist oppdatert: 2011-01-10bibliografisk kontrollert

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