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Modelling the kraft pulping process on a fibre scale by considering the intrinsic heterogeneous nature of the lignocellulosic feedstock
Mid Sweden University, Faculty of Science, Technology and Media, Department of Chemical Engineering. (FSCN)
Mid Sweden University, Faculty of Science, Technology and Media, Department of Chemical Engineering. Aalto University, Finland. (FSCN)
2022 (English)In: Chemical Engineering Journal, ISSN 1385-8947, E-ISSN 1873-3212, Vol. 438, article id 135548Article in journal (Refereed) Published
Abstract [en]

Renewable raw materials such as lignocellulose are inherently complex and demanding in chemical processing compared to petroleum-based feedstocks. This article addresses the challenge of developing a general model framework for modelling lignocellulosic feedstock on a fibre scale, considering its inherent heterogeneous nature in terms of the fundamental chemical component distribution in addition to its anisotropic structural properties. The presented model is tested and validated for the well-established kraft pulping process. Simulations and parameter estimation are carried out to investigate the kappa number distribution of softwood fibres during kraft pulping by using experimental data from the literature showing non-uniform delignification. A moving grid discretisation method for the distributed concentration variables is used to predict the reaction of the wood solids. The results suggest that an inherent fundamental chemical component distribution can be hypothesised as one source of the non-uniform delignification. The model indicates that a Gaussian distribution can be assumed for the initial lignin concentration within softwood. In addition, an investigation of the lignin kinetics suggests that the reactivity of lignin during kraft pulping decreases as the delignification progresses. 

Place, publisher, year, edition, pages
2022. Vol. 438, article id 135548
Keywords [en]
Chemical pulp, Digester, Distribution, Kappa number, Lignin reactivity, Uniformity
National Category
Paper, Pulp and Fiber Technology
Identifiers
URN: urn:nbn:se:miun:diva-44602DOI: 10.1016/j.cej.2022.135548ISI: 000779738200003Scopus ID: 2-s2.0-85125791162OAI: oai:DiVA.org:miun-44602DiVA, id: diva2:1644829
Available from: 2022-03-15 Created: 2022-03-15 Last updated: 2022-05-05Bibliographically approved

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Fiskari, JuhaAlopaeus, Ville

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