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Beyond averages – some aspects of how to describe a heterogeneous material, mechanical pulp, on particle level
Mid Sweden University, Faculty of Science, Technology and Media, Department of Chemical Engineering.
2021 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

For a more profound understanding of how a process works, it is essential to have a relevant description of the material being processed. With this description, it will be easier to evaluate and control processes to produce more uniform products with the right properties. The focus of this thesis is on how to describe mechanical pulps in ways that reflect its character.

Mechanical pulps are made from wood, a highly heterogeneous material. Common practice within the pulping industry and academy is to describe mechanical pulps and its wide variety of particles in terms of averages. The energy efficiency of the mechanical pulping process is usually calculated without taking into account the characteristics of the wood fed to the process. The main objective of the thesis is to explore ways to make more detailed descriptions of mechanical pulps. A second objective is to propose useful ways to visualise these descriptions.

The studies were carried out in full-scale mill operations for TMP of publication grades and CTMP for board grades with Norwegian spruce as raw material. The particles in the pulps were analysed in an optical particle analyser for several properties such as length, curl, wall thickness, diameter,and external fibrillation for 10,000 to 60,000 particles per sample to cover their wide property variation. The data was analysed by factor analysis, a method to reduce the multidimensional data space, and also compared with data simulations.

Several examples were identified where averages based on wide and skewed distributions may hide useful information and therefore result in misleading conclusions regarding the fibrous material and process performance. A method was developed to calculate the distribution of a common bonding factor, BIND (bonding indicator) for individual particles. This factor is calculated from external fibrillation, wall thickness and diameter measured in an optical particle analyser. Distributions of BIND is one way to characterize and visualise the heterogeneity of mechanical pulp. A characteristic BIND-distribution is set in the primary refiner stage, depending on both wood and process conditions and remains mostly intact through the process.

It was demonstrated that both BIND-distributions and 4D maps of the measured property distributions could be used to assess the tails of the distributions (extreme values), energy efficiency, and fractionation efficiency in a new way. It was even possible to get a measure for energy efficiency for a primary stage refiner, since a method was developed where the wood raw material was evaluated in the same way as the pulp discharged from the refiner.

It was demonstrated that the average length-length-weighted fibre length, commonly referred to as the average weight-weighted fibre length, is a relevant way to express the amount of long fibres, i.e. “length factor”. The commonly used average length-weighted fibre length may lead to erroneous conclusions. Through data simulations of curl and fibre length on particle level it was found that today’s analysers may underestimate the true length of the particles, especially if they are prone to be curled. As a result, theranking of pulps may be altered.

It was concluded that although there is an ISO standard, or long-time used property, it does not necessarily imply that it is a relevant method. Misleading conclusions may be drawn based on current methods; here, modifications of these methods are suggested.

The main contribution of this study is the finding that that a highly heterogeneous material such as mechanical pulps could be described in new ways through visualisation of data in 4D maps. These maps reveal casualconnections and more pertinent questions may be raised in thecommunication along the chain product-pulp-wood.

Going beyond averages may reveal discrepancies in the process and material that were previously unknown, and lead to a more profound understanding. It seems that the mechanical pulping process can be even further simplified than previously expected. It has been concluded that to operate the process more efficiently, and for make products with just the right quality, the main focus should be on the raw material and the primary refiner stage from a heterogeneity point of view.

Abstract [sv]

För att få en fördjupad förståelse av hur en process fungerar är det väsentligt att ha en relevant beskrivning av materialet som processas. Det gör det enklare att utvärdera och styra processer för att tillverka produkter med jämn kvalitet med just de rätta egenskaperna. Fokuset i denna avhandling är hur mekaniska massor kan beskrivas för att reflektera deras karaktär.

Mekaniska massor är gjorda av ved som är ett mycket heterogent material. Inom massaindustrin och den akademiska världen beskrivs nästan uteslutande mekaniska massor och dess stora variation av partiklar i form av medelvärden. Energieffektivitet hos processer för mekaniska massor beräknas vanligtvis utan att ta hänsyn till hur vedråvaran är beskaffad. Huvudmålet med denna avhandling var att undersöka sätt att ge en mer detaljerad beskrivning av mekaniska massor. Ett andra mål var att föreslå användbara sätt att visualisera beskrivningarna.

Undersökningarna genomfördes i fabriksskala för termomekanisk massa (TMP) för tryckpapper respektive kemitermomekansik massa (CTMP) förkartong, alla med gran som råvara. Partiklarna som utgör massa analyserades in en optisk partikelanalysator som mätte egenskaper såsom längd, curl (krokighet), väggtjocklek, diameter samt extern fibrillering. För att täcka den stora variationen i partiklarnas egenskaper mättes för varje prov 10 000 till 60 000 partiklar. Data analyserades med faktoranalys, en matematisk metod at kondensera datarymden. Dessutom modellerades samband mellan fiberegenskaper med datasimulering.

Åtskilliga exempel visades där medelvärden baserade på breda och skeva fördelningar kan dölja användbar information och därmed ge missvisande slutsatser vad avser såväl fibermaterialet som processen. En metod utvecklades för att beräkna distributionen av en så kallad gemensam bindningsfaktor, BIND (bonding indicator) på partikelnivå. Denna faktor är beräknad ifrån extern fibrillering, väggtjocklek samt diameter mätta in en optisk partikelanalysator. Fördelningen av BIND är ett sätt att beskriva och visualisera heterogeniteten hos mekaniska massor. En karaktäristisk BIND fördelning skapas i det först raffineringssteget, beroende på både veden och processbetingelserna, och bibehålls nästan intakt i de följande processtegen.

Det visades att både BIND-fördelningarna samt fyrdimensionella kartor baserat på rådata av partikelegenskaperna kunde användas för att beskriva ”svansar” i distributionerna (extremvärden). Dessutom är det möjligt att på ett nytt sätt få mått på energieffektivitet samt fraktioneringseffektivitet. Till och med energieffektivitet hos ett primärraffineringssteg var möjligt att få ett mått på eftersom vedråvaran utvärderades på samma sätt som massan som kom ut från nämnda processteg.

Vidare visades det att längd-längd-viktat medelvärde av fiberlängd, även benämnt vikt-viktat medelvärde, är ett relevant mått för att uttrycka andelen långfiber i en massa. Det vanligtvis inom branschen använda längd-viktademedelvärdet av fiberlängd kan leda till felaktiga slutsatser. Genom datasimulering av curl och fiberlängd på partikelnivå framkom det att dagens fiberanalysatorer kan undervärdera den verkliga längden hos partiklar särskilt om de är curlade. Rangordningen av massor kan bli omkastad.

Trots att det finns ISO standarder eller under lång tid använda egenskaper innebär det inte att det är en relevant metod utan kan leda till att felaktiga slutsatser dras. Modifiering av existerande metoder samt nya metoder har föreslagits.

En viktig slutsats i denna avhandling är att ett mycket heterogent material, såsom mekaniska massor, är möjliga att beskriva genom visualisering av data i form av fyrdimensionella kartor. Dessa visar på orsakssamband samt underlättar kommunikationen i kedjan produkt-massa-ved. Mer relevanta frågor är därmed möjliga att ställa.

Genom att gå bortom medelvärden är det möjligt att upptäcka avvikelser i processen och materialet, icke kända tidigare, och ge en mer grundläggande förståelse. Det finns starka indikationer på att den mekaniska massaprocessen är möjlig att förenkla mer än tidigare antagits. Dessutom kan slutsatser dras hur processen kan köras effektivare och göra det möjligt att tillverka produkter med rätt kvalitet genom att fokusera på vedråvaran samt primärraffineringssteget, allt utifrån från ett heterogenitetsperspektiv.

Place, publisher, year, edition, pages
Sundsvall: Mid Sweden University , 2021. , p. 134
Series
Mid Sweden University doctoral thesis, ISSN 1652-893X ; 347
Keywords [en]
Visualisation, Uniformity, Distributions, Independent common factors, Weighted fibre length, Fibre bonding, Fibrillation, Curl, Wall thickness, Particle analyser characterisation, Raw material, CTMP, Process configuration, Sampling accuracy
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:miun:diva-42060ISBN: 978-91-89341-09-8 (print)OAI: oai:DiVA.org:miun-42060DiVA, id: diva2:1555454
Public defence
2021-06-04, C312 och Online, Holmgatan 10, Sundsvall, 13:00 (English)
Opponent
Supervisors
Note

Vid tidpunkten för disputationen var följande delarbeten opublicerade: delarbete 5 inskickat, delarbete 7 manuskript.

At the time of the doctoral defence the following papers were unpublished: paper 5 submitted, paper 7 manuscript.

Available from: 2021-05-18 Created: 2021-05-18 Last updated: 2021-05-18Bibliographically approved
List of papers
1. Improved quality control and process design in production of mechanical pulp by use of factor analysis
Open this publication in new window or tab >>Improved quality control and process design in production of mechanical pulp by use of factor analysis
1997 (English)In: Proceedings International Mechanical Pulping Conference, 1997, p. 111-125Conference paper, Published paper (Refereed)
Abstract [en]

In 1963, Forgacs showed that at least two quality variables are needed in order to characterize the quality of mechanical pulps. Later, Strand came to asimilar conclusion by introducing two independent common factors through the use of factor analysis. Both Forgacs and Strand showed that handsheet properties can be predicted from these two factors. This paper shows how STORA, on the basis of Strand’s approach, examines the two independent common factors directly, instead of examining a large amount of conventional measured pulp and handsheet properties. The factors are called F1, fibrebonding, and F2, long fibre influence. The independent factors are controlled to a great extent by independent process parameters; F1 correlates more strongly to specific energy than does freeness while F2 is mainly controlled by conditions in the defibration stage. In order to produce a uniform pulp quality, F1 and F2 should be kept inside a specified quality window. Since July 1995 a quality window in terms of F1 and F2 has been used at STORA Kvarnsveden TMP plant and thus has given a more stable pulp quality. The quality window gives a rapid overview of the status of the quality. Another advantage of applying F1 and F2 is that not only refiners, but also screens and cleaners can be evaluated in terms of the same quality variables. New parameters for evaluation of screens and cleaners are suggested. By examining all process stages from chip refiner, screen room to final pulp we can get a quality map in terms of F1 and F2. From this map it is quite obvious how the pulp quality is influenced by chip refiner stage and rejects refining. The F1/F2-map can simplify the work to find reasons for producing off-spec pulp and also mee tone big challenge: to produce a product of more uniform quality. To attain more uniform quality we have to think and speak daily in terms of factors like F1 and F2.

National Category
Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:miun:diva-42068 (URN)
Conference
International Mechanical Pulping Conference, Stockholm, 1997
Available from: 2021-05-18 Created: 2021-05-18 Last updated: 2021-05-18Bibliographically approved
2. Process considerations and its demands on TMP property measurements - A study on tensile index
Open this publication in new window or tab >>Process considerations and its demands on TMP property measurements - A study on tensile index
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2017 (English)In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, E-ISSN 2000-0669, Vol. 32, no 1, p. 45-53Article in journal (Refereed) Published
Abstract [en]

As a vital component in the strive towards improved energy efficiency in the operation of TMP refining processes, this work highlights the importance of well- designed procedures when collecting and analysing pulp properties with respect to process conditions. Process data and pulp from a CD82 chip refiner have been used to show that tensile index has strong covariance with fibre residence time calculated by the extended entropy model. A combination of theoretical and practical analysis methods has shown that, in order to assure representative, reliable results, pulp sampling procedures should comprise composite pulp samples collected during a sampling period of about three minutes. In addition, at least four subsequently collected composite pulp samples should be included in the analysis to effectively dampen effects from fast process variations as well as from slow process drift. An in-depth study on tensile index measurements clarifies that 40-60 strips should be used in the case we studied regardless if machine made paper or handsheets are considered.

Keywords
Accuracy, Composite pulp samples, Pulp sampling procedure, Residence time, Tensile index, TMP
National Category
Chemical Engineering
Identifiers
urn:nbn:se:miun:diva-30666 (URN)10.3183/NPPRJ-2017-32-01-p045-053 (DOI)000398384400006 ()2-s2.0-85016389492 (Scopus ID)
Available from: 2017-04-26 Created: 2017-04-26 Last updated: 2021-05-18Bibliographically approved
3. Measuring the bonding ability distribution of fibers in mechanical pulps
Open this publication in new window or tab >>Measuring the bonding ability distribution of fibers in mechanical pulps
2008 (English)In: TAPPI Journal, ISSN 0734-1415, Vol. 7, no 12, p. 26-32Article in journal (Refereed) Published
Abstract [en]

Currently, the pulp and paper industry mainly uses average values of   mechanical pulp properties to characterize fibers, while printing paper   grammages keep decreasing, making every fiber more important for   strength, surface, and structure properties. Because fibers are   inhomogeneous, average values of the whole pulp may not be enough for   proper fiber characterization. This paper reports results from the   development of a method to measure the distribution of fiber bonding   ability in mechanical pulps.   Fibers from two commercial TMPs were fractionated into five   hydrocyclone streams, using a four-stage hydrocyclone system. The fiber   bonding ability of Bauer McNett fractions R16, P16/R30 and P30/R50   collected from each stream was analyzed. Five different methods of   evaluating fiber bonding ability all showed that fibers were separated   in the hydrocyclones according to their bonding ability.   Long fiber handsheets of the highest bonding fibers had up to 2.5 times   higher tensile strength for the P16/1330 fraction than handsheets from   the lowest bonding fibers. We also found that both the degree of   fibrillation and collapse resistance index (CRI) of the fibers obtained   from optical measurements are sufficient to predict quite accurately   the tensile strength of handsheets made from fiber fractions. Further,   we propose how to describe the distribution in fiber bonding ability   for mechanical pulps, by combining some of these five different   methods. A method to calculate fracture toughness of long fiber   handsheets based on acoustic emission is also illustrated.   A more rapid way to characterize fibers in mechanical pulps with   respect to their bonding ability distribution needs to be developed in   the future. It appears that it is time to move on from characterizing   pulp suspensions and handsheet properties using conventional approaches   based on average values.

National Category
Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:miun:diva-7381 (URN)000262544300005 ()2-s2.0-58749097112 (Scopus ID)
Available from: 2008-12-09 Created: 2008-12-05 Last updated: 2021-05-18Bibliographically approved
4. The influence of fiber dimensions on mechanical pulp long fiber tensile index and density
Open this publication in new window or tab >>The influence of fiber dimensions on mechanical pulp long fiber tensile index and density
2012 (English)In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, E-ISSN 2000-0669, Vol. 27, no 5, p. 844-859Article in journal (Refereed) Published
Abstract [en]

This study discusses how fiber dimensions affect the tensile index and density of long fiber laboratory sheets. Five commercial mechanical pulps (three TMP grades, one SGW and one CTMP) were fractionated into five streams in a hydrocyclone pilot plant. Fiber dimensions and fibrillation were analyzed of the P16/R30 and P30/R50 fractions and compared to the sheet properties. For comparison, samples were also analyzed by SEM cross-sectional image analysis and in a MorFi Lab optical analyzer. Fibrillation index showed a high positive influence on long fiber tensile index and density, whereas fiber wall thickness, fiber width, and collapse resistance index a negative. Fiber width showed the vaguest correlation to long fiber tensile index and density of the analyzed fiber properties, but this increased when combined with fiber wall thickness into collapse resistance index, CRI. The correlations between fiber properties and sheet properties were on different levels for the different mechanical pulping processes, but a combination of collapse resistance index and fibrillation index into the novel factor BIN, Bonding ability INfluence, gave one linear relation of high correlation to long fiber tensile index for all pulps, except the SGW P30/R50 fraction, which showed the same linear correlation on a slightly lower level. BIN should be a useful tool in characterizing mechanical pulp fibers.

Keywords
Bonding ability, Collapse resistance, Fiber characterization, Fiber wall thickness, Fiber width, FiberLab, Fibrillation, Mechanical pulp, MorFi Lab, Optical analyzer, SEM image analysis, Sheet properties
National Category
Chemical Engineering
Identifiers
urn:nbn:se:miun:diva-18300 (URN)10.3183/NPPRJ-2012-27-05-p844-859 (DOI)000313375400003 ()2-s2.0-84871766130 (Scopus ID)
Note

Language of Original Document: English

Available from: 2013-04-04 Created: 2013-01-16 Last updated: 2021-05-18Bibliographically approved
5. Heterogeneity of Thermomechanical and Chemi-thermomechanical Pulps described with distributions of an independent common bonding factor on particle level
Open this publication in new window or tab >>Heterogeneity of Thermomechanical and Chemi-thermomechanical Pulps described with distributions of an independent common bonding factor on particle level
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2022 (English)In: BioResources, E-ISSN 1930-2126, Vol. 17, no 1, p. 763-784Article in journal (Refereed) Published
Abstract [en]

Particles in mechanical pulp show a wide variety but are commonly described using averages and/or collective properties. The authors suggest using distributions of a common bonding factor, BIND (Bonding INDicator), for each particle. The BIND-distribution is based on factor analysis of particle diameter, wall thickness, and external fibrillation of several mechanical pulps measured in an optical analyser. A characteristic BIND-distribution is set in the primary refiner, depending on both wood and process conditions, and remains almost intact along the process. Double-disc refiners gave flatter distributions and lower amounts of fibres with extreme values than single-disc refiners. More refining increased the differences between fibres with low and high BIND. Hence, it is more difficult to develop fibres with lower BIND. Examples are given of how BIND-distributions may be used to assess energy efficiency, fractionation efficiency, and influence of raw material. Mill scale operations were studied for printing-grade thermomechanical pulp (TMP), and board-grade chemi-thermomechanical pulp (CTMP), both from spruce.

Keywords
Heterogeneity, Distributions, Spruce, TMP, CTMP, Wood fibres, Fibre analyser, Fibre bonding, External fibre fibrillation, Fibre wall thickness
National Category
Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:miun:diva-42061 (URN)10.15376/biores.17.1.763-784 (DOI)000760918300002 ()2-s2.0-85137275487 (Scopus ID)
Available from: 2021-05-18 Created: 2021-05-18 Last updated: 2024-07-04Bibliographically approved
6. Average fibre length as a measure of the amount of long fibres in mechanical pulps - ranking of pulps may shift
Open this publication in new window or tab >>Average fibre length as a measure of the amount of long fibres in mechanical pulps - ranking of pulps may shift
2018 (English)In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, E-ISSN 2000-0669, Vol. 33, no 3, p. 468-481Article in journal (Refereed) Published
Abstract [en]

The purpose of this study was to investigate the applicability of different ways of calculating the average fibre length based on length measurements of individual particles of mechanical pulps. We have found that the commonly used average length-weighted fibre length, which is based on the assumption that coarseness is constant for all particles, as well as the arithmetic average, may lead to erroneous conclusions in real life as well as in simulations when used as a measure of the amount of long fibres. The average length-length-weighted fibre length or a weighting close to that, which to a larger extent suppresses the influence of shorter particles, is a relevant parameter of the "length" factor, i. e. amount of long fibres. Our findings are based on three studies: refining of different assortments of wood raw material in a mill; data from LC refining in mill of TMP, including Bauer McNett fractionation; mixing of pulps with different fibre length distributions. If the acceptable average fibre length for different products can be lowered, the possibility of reducing the specific energy input in refining will increase. Therefore, we need a reliable and appropriate way to assess the "length" factor.

Keywords
average fibre length, fibres, fines, long fibres, mechanical pulp, weighted length
National Category
Chemical Engineering
Identifiers
urn:nbn:se:miun:diva-35160 (URN)10.1515/npprj-2018-3058 (DOI)000450923900013 ()2-s2.0-85047975413 (Scopus ID)
Available from: 2018-12-11 Created: 2018-12-11 Last updated: 2021-05-18Bibliographically approved
7. Heterogeneity of mechanical pulp particles - variations and correlations beyond averages
Open this publication in new window or tab >>Heterogeneity of mechanical pulp particles - variations and correlations beyond averages
Show others...
(English)Manuscript (preprint) (Other academic)
National Category
Chemical Engineering
Identifiers
urn:nbn:se:miun:diva-42071 (URN)
Available from: 2021-05-18 Created: 2021-05-18 Last updated: 2021-10-21Bibliographically approved

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